On the 2005 Australian Junior Championships, Mitchell completed seventh within the all-round, balance beam, and floor exercise and eighth on the uneven bars. In March, Mitchell competed on the Pacific Rim Championships where the Australian team finished fourth. In October, just after turning 19, Mustafina competed at the 2013 World Artistic Gymnastics Championships in Antwerp. Then in October, she competed at the World Championships at the O2 Arena in London. She then competed at the Moscow World Cup where she completed fifth on each the uneven bars and the balance beam. Her final competition of the season was the Toyota Cup where she received the gold medal on the stability beam. In her first year of senior competition, Mitchell certified for the stability beam event remaining at the 2007 World Championships. In July, Mitchell won gold medals within the all-round, vault, balance beam, and floor exercise at the Australian Championships. She went on to win two silver medals in the occasion finals, on the ground exercise behind Great Britain's Beth Tweddle and on the stability beam behind China's Deng Linlin.
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